Recent advances in the nickel-catalyzed alkylation of C-H bondsPožgan, Franc (Avtor) Grošelj, Uroš (Avtor) Svete, Jurij (Avtor) Štefane, Bogdan (Avtor) Al Mamari, Hamad (Avtor) nickelC-H activationcatalysisC-H bond functionalizationC-H bond alkylationNi-catalysischelation assistancecyclometalationFunctionalization of C-H bonds has emerged as a powerful strategy for converting inert, nonfunctional C-H bonds into their reactive counterparts. A wide range of C-H bond functionalization reactions has become possible by the catalysis of metals, typically from the second row of transition metals. First-row transition metals can also catalyze C-H functionalization, and they have the merits of greater earth-abundance, lower cost and better environmental friendliness in comparison to their second-row counterparts. C-H bond alkylation is a particularly important C-H functionalization reaction due to its chemical significance and its applications in natural product synthesis. This review covers Ni-catalyzed C-H bond alkylation reactions using alkyl halides and olefins as alkyl sources.20242024-06-12 10:14:36Članek v reviji158451UDK: 547:66.095.253:546.74ISSN pri članku: 1420-3049DOI: 10.3390/molecules29091917COBISS_ID: 198576899sl