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<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:dc="http://purl.org/dc/elements/1.1/"><rdf:Description rdf:about="https://repozitorij.uni-lj.si/IzpisGradiva.php?id=175444"><dc:title>Revisiting the coordination chemistry of molybdenum(V)</dc:title><dc:creator>Modec,	Barbara	(Avtor)
	</dc:creator><dc:creator>Podjed Rihtaršič,	Nina	(Avtor)
	</dc:creator><dc:subject>molybdenum(V)</dc:subject><dc:subject>picolinate</dc:subject><dc:subject>pyrazinoate</dc:subject><dc:subject>crystal structure</dc:subject><dc:description>Reactions of (pyH)$_5$[MoOCl$_4$(H$_2$O)]$_3$Cl$_2$ with picolinic and pyrazinoic acids yielded three new dinuclear molybdenum(V) complexes: (pyH)$_2$[Mo$_2$O$_4$Cl$_2$(pic)$_2$]·CH$_3$CN (1), (pyH)$_2$[Mo$_2$O$_4$Cl$_2$(pic)$_2$]·CH$_3$CH$_2$CN (2) and (pyH)$_2$[Mo$_2$O$_4$Cl$_2$(pyraz)$_2$]·CH$_3$CN (3) (pic$^−$ = picolinate, pyraz$^−$ = pyrazinoate and pyH$^+$ = protonated pyridine). The compounds were characterized by single-crystal X-ray diffraction, infrared and $^1$H NMR spectroscopy, elemental analysis, and TG/DSC measurements. All display a robust {Mo$^V_2$O$_4$}$^{2+}$ core with the heteroaromatic ligands bound in a N,O-bidentate chelating manner.</dc:description><dc:date>2025</dc:date><dc:date>2025-10-28 08:27:37</dc:date><dc:type>Članek v reviji</dc:type><dc:identifier>175444</dc:identifier><dc:language>sl</dc:language></rdf:Description></rdf:RDF>