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<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:dc="http://purl.org/dc/elements/1.1/"><rdf:Description rdf:about="https://repozitorij.uni-lj.si/IzpisGradiva.php?id=160778"><dc:title>Chloroimidazolium deoxyfluorination reagent with H$_2$F$_3$$^–$ anion as a sole fluoride source</dc:title><dc:creator>Prinčič,	Griša Grigorij	(Avtor)
	</dc:creator><dc:creator>Omahen,	Blaž	(Avtor)
	</dc:creator><dc:creator>Jelen,	Jan	(Avtor)
	</dc:creator><dc:creator>Gruden,	Evelin	(Avtor)
	</dc:creator><dc:creator>Tavčar,	Gašper	(Avtor)
	</dc:creator><dc:creator>Iskra,	Jernej	(Avtor)
	</dc:creator><dc:subject>alcohols</dc:subject><dc:subject>anions</dc:subject><dc:subject>organic acids</dc:subject><dc:subject>pharmaceuticals</dc:subject><dc:subject>reagents</dc:subject><dc:description>In the study, we introduce an air-stable NHC-based deoxyfluorination reagent ImCl[H$_2$F$_3$], offering a promising avenue for deoxyfluorination across various substrates. Reagent efficiently fluorinates benzyl alcohols, carboxylic acids, and P(V) compounds without external fluoride sources. A mechanistic study reveals a twostep process involving benzyl chloride as an intermediate, shedding light on the two-step reaction pathway. The Hammet plot provides insights into reaction mechanisms with different substrates, enhancing our understanding of this versatile deoxyfluorination method.</dc:description><dc:date>2024</dc:date><dc:date>2024-09-04 13:23:23</dc:date><dc:type>Članek v reviji</dc:type><dc:identifier>160778</dc:identifier><dc:language>sl</dc:language></rdf:Description></rdf:RDF>