Polymethylenetetrazole : synthesis, characterization, and energetic properties

Brenjo, Ljubica (avtor), Oklješa, Aleksandar (avtor), Tomšič, Matija (avtor), Barta Holló, Berta (avtor), Nešić, Jovica (avtor), Tóth, Elvira (avtor), Podlipnik, Črtomir (avtor)

The tetrazole moiety remains one of the most interesting scaffolds in the development of new high-energy density materials (HEDMs) because of its desired characteristics, such as high nitrogen content and heat of formation (HOF). The combination of several heterocycles with high HOF seems to be a promising strategy for obtaining energetic materials with superior properties. Herein, we report the synthesis and characterization of a tetrazole polymer, polymethylenetetrazole (PMT), as a potential HEDM. The compound was characterized using NMR, IR, and Raman spectroscopy. Its weight average molecular mass was obtained by static light scattering (SLS), and its physical properties by powder XRD analysis. The density, sensitivity to friction (FS), and impact (IS) of the compound were determined as well. The results of the thermal and energetic properties of PMT suggest that this polymer could be an insensitive explosive.

• Jezik: Angleški jezik
• Ključne besede: tetrazoles, polymers, high-energy density materials
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Status publikacije: Objavljeno
• Različica publikacije: Objavljena publikacija
• Leto izida: 2024
• Št. strani: 13 str.
• Številčenje: Vol. 29, iss. 14, art. 3389
• PID: 20.500.12556/RUL-181557
• UDK: 547.79:678
• ISSN pri članku: 1420-3049
• DOI: 10.3390/molecules29143389
• COBISS.SI-ID: 270394371
• Datum objave v RUL: 10.04.2026

Gradivo je del revije

• Naslov: Molecules
• Skrajšan naslov: Molecules
• Založnik: MDPI
• ISSN: 1420-3049
• COBISS.SI-ID: 18462981

Licence

• Licenca: CC BY 4.0, Creative Commons Priznanje avtorstva 4.0 Mednarodna
• Povezava: http://creativecommons.org/licenses/by/4.0/deed.sl
• Opis: To je standardna licenca Creative Commons, ki daje uporabnikom največ možnosti za nadaljnjo uporabo dela, pri čemer morajo navesti avtorja.

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: tetrazoli, polimeri, materiali z visoko energijsko gostoto