Theory of ultrafast screening of U in driven charge-transfer insulators: a time-resolved x-ray absorption study

Golež, Denis (avtor), Paprotzki, Eva (avtor), Werner, Philipp (avtor), Eckstein, Martin (avtor)

Recent seminal experiments have utilized time-resolved x-ray absorption spectroscopy (XAS) to investigate the ultrafast photoinduced renormalization of the electron interaction (“Hubbard U”) in Mott and charge transfer insulators. In this paper, we theoretically analyze the change of interactions due to dynamical screening as it is encoded in the XAS signal, using the nonequilibrium GW+EDMFT formalism. Our study shows that XAS is well-suited for measuring this change, but two aspects should be kept in mind if the screening processes are not substantially faster than the valence electron dynamics: (i) Screening in a photoexcited system can affect both the position and the lineshape of the absorption lines. (ii) In general, the effect cannot be captured by the modification of a single interaction parameter. Specifically, an estimate for Δ⁢� extracted from the shift of the XAS lines does not necessarily describe the related shift of the upper Hubbard band. We clarify these aspects using a minimal cluster model and the three-band Emery model for a charge transfer insulator.

• Jezik: Angleški jezik
• Ključne besede: consensed matter physics, nonequilibrium systems, Hubbard model, X-ray absorption spectroscopy
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FMF - Fakulteta za matematiko in fiziko
• Status publikacije: Objavljeno
• Različica publikacije: Recenzirani rokopis
• Leto izida: 2025
• Št. strani: Str. 045147-1-045147-15
• Številčenje: Vol. 111, iss. 4
• PID: 20.500.12556/RUL-177724
• UDK: 538.9
• ISSN pri članku: 2469-9950
• DOI: 10.1103/PhysRevB.111.045147
• COBISS.SI-ID: 233516291
• Datum objave v RUL: 05.01.2026

Gradivo je del revije

• Naslov: Physical review
• Založnik: American Physical Society
• ISSN: 2469-9950
• COBISS.SI-ID: 2997348

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: fizika kondenzirane snovi, neravnovesni sistemi, Hubbardov model, rentgenska absorpcijska spektroskopija