Oxygen-promoted on-surface synthesis of polyboroxine molecules

Toffoli, Daniele (avtor), Kladnik, Gregor (avtor), Cvetko, Dean (avtor)

We present a protocol for the on-surface synthesis of polyboroxine molecules derived from boroxine molecules precursors. This process is promoted by oxygen species present on the Au(111) surface: oxygen atoms facilitate the detachment of naphthalene units of trinaphthyl-boroxine molecules and bridge two unsaturated boroxine centers to form a boroxine-O-boroxine chemical motif. X-ray spectroscopic characterization shows that, as the synthesis process proceeds, it progressively tunes the electronic properties of the interface, thus providing a promising route to control the electron level alignment.

• Jezik: Angleški jezik
• Ključne besede: physical chemistry
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FMF - Fakulteta za matematiko in fiziko
• Status publikacije: Objavljeno
• Različica publikacije: Recenzirani rokopis
• Leto izida: 2024
• Št. strani: 6 str.
• Številčenje: Vol. 30, iss. 47, art. no. e202401565
• PID: 20.500.12556/RUL-176879
• UDK: 544
• ISSN pri članku: 0947-6539
• DOI: 10.1002/chem.202401565
• COBISS.SI-ID: 223124227
• Datum objave v RUL: 12.12.2025

Gradivo je del revije

• Naslov: Chemistry : a European journal
• Skrajšan naslov: Chemistry
• Založnik: Wiley, Chemistry Europe
• ISSN: 0947-6539
• COBISS.SI-ID: 16938501

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: fizikalna kemija