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Fotokatalitska razgradnja farmacevtskih onesnaževal pod UV in vidno svetlobo
ID Godnjavec, Karin (Avtor), ID Lavrenčič Štangar, Urška (Mentor) Več o mentorju... Povezava se odpre v novem oknu, ID Žener, Boštjan (Komentor)

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Izvleček
Farmacevtiki sodijo med organska onesnaževala, ki jih najpogosteje zaznamo v vodnem okolju (v odpadni vodi, podtalnici, tleh, površinskih vodah in živih organizmih). Njihova prisotnost močno vpliva na okolje in zdravje ljudi, živali. S tem razlogom se je začel razvoj raziskav in postopkov za razgradnjo farmacevtskih onesnaževal. Heterogena fotokataliza na osnovi TiO$_2$ predstavlja eno najbolj obetavnih metod za odstranjevanje farmacevtskih onesnaževal iz odpadne vode. Na tej metodi temeljijo raziskave, ki sem jih izvedla v okviru svoje diplomske naloge. Uporabnost TiO$_2$ kot fotokatalizatorja temelji na njegovi visoki aktivnosti, kemični in biološki stabilnosti ter cenovni dostopnosti. Namen raziskave je bil preveriti, kako dobro se izbrana farmacevtska onesnaževala fotokatalitsko razgrajujejo pod UV in vidno svetlobo. V ta namen sem sprva s hidrotermalno sintezo pripravila katalizator TiO$_2$, nato je sledila izvedba fotokatalitskih testov. Koncentracijo farmacevtikov sem določila s tekočinsko kromatografijo visoke ločljivosti. Pridobljeni rezultati so pokazali, da so nekateri farmacevtiki manj obstojni od drugih ter so se razgradili v celoti, medtem ko pri ostalih temu ni bilo tako. Fotokatalitske teste sem izvedla še na mešanici petih različnih farmacevtikov in s tem potrdila, da se ti rezultati razlikujejo od rezultatov, dobljenih pri posameznih farmacevtikih. To ponazarja kompleksnost, ki jo povzroči istočasna prisotnost različnih farmacevtskih onesnaževal. Kot je navedeno že v naslovu tega diplomskega dela, sem fotokatalitske teste izvajala med osvetljevanjem z UV in vidno svetlobo. Farmacevtska onesnaževala so se razgrajevala pri uporabi obeh svetil. Razgradnja je bila učinkovitejša, ko je fotokataliza potekala pod UV svetlobo.

Jezik:Slovenski jezik
Ključne besede:fotokatalizator titanov dioksid, hidrotermalna sinteza, fotokataliza, farmacevtska onesnaževala, čiščenje odpadnih voda
Vrsta gradiva:Diplomsko delo/naloga
Tipologija:2.11 - Diplomsko delo
Organizacija:FKKT - Fakulteta za kemijo in kemijsko tehnologijo
Leto izida:2024
PID:20.500.12556/RUL-159057 Povezava se odpre v novem oknu
COBISS.SI-ID:202670083 Povezava se odpre v novem oknu
Datum objave v RUL:28.06.2024
Število ogledov:282
Število prenosov:68
Metapodatki:XML DC-XML DC-RDF
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Sekundarni jezik

Jezik:Angleški jezik
Naslov:Photocatalytic degradation of pharmaceutical pollutants under UV and visible light
Izvleček:
Pharmaceuticals are among the organic pollutants most frequently detected in the aquatic environment (in wastewater, groundwater, soil, surface water and living organisms). Their presence has a strong impact on the environment and on human and animal health. For this reason, the development of research and processes for the degradation of pharmaceutical pollutants has begun. Heterogeneous photocatalysis based on TiO$_2$ is one of the most promising methods for removing pharmaceutical pollutants from wastewater. This method is the basis for the research that was conducted as part of my diploma thesis. The usefulness of TiO$_2$ as a photocatalyst is based on its high activity, its chemical and biological stability and its affordability. The aim of the study was to test how well selected pharmaceutical pollutants are photocatalytically degraded under UV and visible light. For this purpose, the TiO$_2$ catalyst was first prepared by hydrothermal synthesis and then photocatalytic tests were carried out. The concentration of the pharmaceuticals was determined using high-resolution liquid chromatography. The results showed that some pharmaceuticals were less persistent and were completely degraded, while others were not. Photocatalytic tests were also performed with a mixture of five different pharmaceuticals and confirmed that these results differed from the results obtained with single pharmaceuticals. This illustrates the complexity created by the simultaneous presence of different pharmaceutical contaminants. As mentioned in the title of this thesis, the photocatalytic tests were performed under UV and visible light. Pharmaceutical pollutants were degraded when both light source was used. The degradation was more efficient when photocatalysis took place under UV light.

Ključne besede:photocatalyst titanium dioxide, hydrothermal synthesis, photocatalysis, pharmaceutical pollutants, wastewater treatment

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