Nanocrystallization of Bi$_2$O$_3$ based system from the glassy state under high compression

Szpakiewicz-Szatan, Aleksander (avtor), Pietrzak, Tomasz K. (avtor), Sierakowski, Kacper (avtor), Boćkowski, Michał (avtor), Rzoska, Sylwester (avtor), Garbarczyk, Jerzy E. (avtor), Starzonek, Szymon (avtor)

This report presents the pressure-temperature (p-T) plane of Bi$_2$O$_3$-Al$_2$O$_3$-SiO$_2$ ternary system in the context of nanocrystallite formation from its amorphous state. The diagram was constructed through differential thermal analysis (DTA) performed in situ under high-pressure-high-temperature (HP-HT) conditions, with nitrogen serving as the pressurizing medium. Above the glass transition temperature T$_g$, a wide ultraviscous, supercooled liquid state spanning approximately 150 K is observed. Later heating transforms this state into nanocrystallites embedded within an amorphous matrix, thereby keeping distinctive structural characteristics even after the decompression process. The p-T plane serves as a fundamental prerequisite for the design of nanocrystallites within a glass matrix, a well-established technique known as glass-ceramics. Various paths within the p-T plane, followed by annealing just below T$_g$, can be explored, potentially leading to the development of Bi$_2$O$_3$-based materials with enhanced electrical, dielectric, photonic, and mechanical properties, predicated on nanocrystallites formed by high-pressure treatment.

• Jezik: Angleški jezik
• Ključne besede: nanocrystalization, Bi$_2$O$_3$, ionic conductor, bismuth oxide, high-pressure, nanocrystallites, p-T plane
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FE - Fakulteta za elektrotehniko
• Status publikacije: Objavljeno
• Različica publikacije: Objavljena publikacija
• Leto izida: 2024
• Št. strani: 6 str.
• Številčenje: Vol. 33, art. 101975
• PID: 20.500.12556/RUL-153060
• UDK: 577
• ISSN pri članku: 2589-1529
• DOI: 10.1016/j.mtla.2023.101975
• COBISS.SI-ID: 176459779
• Datum objave v RUL: 15.12.2023

Gradivo je del revije

• Naslov: Materialia
• Založnik: Elsevier, Acta Materialia Inc.
• ISSN: 2589-1529
• COBISS.SI-ID: 43267075

Licence

• Licenca: CC BY 4.0, Creative Commons Priznanje avtorstva 4.0 Mednarodna
• Povezava: http://creativecommons.org/licenses/by/4.0/deed.sl
• Opis: To je standardna licenca Creative Commons, ki daje uporabnikom največ možnosti za nadaljnjo uporabo dela, pri čemer morajo navesti avtorja.

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: nanokristalizacija, Bi$_2$O$_3$, ionski prevodnik