Development of the new fluoride ion-selective electrode modified with Fe$_x$O$_y$ nanoparticles

Radić, Josip (avtor), Bralić, Marija (avtor), Kolar, Mitja (avtor), Genorio, Boštjan (avtor), Prkić, Ante (avtor), Mitar, Ivana (avtor)

A new modified ion-selective electrode with membranes of LaF$_3$ single crystals with different internal contacts (solid steel or electrolyte) and with Fe$_x$O$_y$ nanoparticles as loading was developed. The best response characteristic with linear potential change was found in the fluoride concentration range from 10$^{−1}$ to 3.98 × 10$^{−7}$ M. The detection limit for the electrolyte contact was determined at 7.41 × 10$^{−8}$ M with a regression coefficient of 0.9932, while the regression coefficient for the solid contact was 0.9969. The potential change per concentration decade ranged from 50.3 to 62.4 mV, depending on whether the contact was solid or electrolytic. The prepared modified electrode has a long lifetime, as well as the possibility of application in different positions (solid contact), and it can also be used for the determination of iron ions. The electrode characterization was performed with scanning electron microscopy and elemental analysis with the technique of electron-dispersive X-ray spectroscopy.

• Jezik: Angleški jezik
• Ključne besede: fluoride ion-selective electrode, nanoparticles, modification, ion-selective electrode, fluoride, metal nanoparticles, internal contact, elemental analysis
• Vrsta gradiva: Članek v reviji
• Tipologija: 1.01 - Izvirni znanstveni članek
• Organizacija: FKKT - Fakulteta za kemijo in kemijsko tehnologijo
• Status publikacije: Objavljeno
• Različica publikacije: Objavljena publikacija
• Leto izida: 2020
• Št. strani: 13 str.
• Številčenje: Vol. 25, iss. 21, art. 5213
• PID: 20.500.12556/RUL-134715
• UDK: 544.6.076.327:620.3
• ISSN pri članku: 1420-3049
• DOI: 10.3390/molecules25215213
• COBISS.SI-ID: 36710915
• Datum objave v RUL: 27.01.2022

RADIĆ, Josip, BRALIĆ, Marija, KOLAR, Mitja, GENORIO, Boštjan, PRKIĆ, Ante in MITAR, Ivana, 2020, Development of the new fluoride ion-selective electrode modified with Fe$_x$O$_y$ nanoparticles. Molecules [na spletu]. 2020. Vol. 25, no. 21,  5213. [Dostopano 7 april 2025]. DOI 10.3390/molecules25215213. Pridobljeno s: https://repozitorij.uni-lj.si/IzpisGradiva.php?lang=slv&id=134715

Gradivo je del revije

• Naslov: Molecules
• Skrajšan naslov: Molecules
• Založnik: MDPI
• ISSN: 1420-3049
• COBISS.SI-ID: 18462981

Licence

• Licenca: CC BY 4.0, Creative Commons Priznanje avtorstva 4.0 Mednarodna
• Povezava: http://creativecommons.org/licenses/by/4.0/deed.sl
• Opis: To je standardna licenca Creative Commons, ki daje uporabnikom največ možnosti za nadaljnjo uporabo dela, pri čemer morajo navesti avtorja.
• Začetek licenciranja: 09.11.2020

Sekundarni jezik

• Jezik: Slovenski jezik
• Ključne besede: fluoridna ionoselektivna eletroda, nanodelci, Fe$_x$O$_y$, modifikacije

Projekti

• Financer: HRZZ - Croatian Science Foundation
• Številka projekta: UIP-2017-05-6282

• Financer: ARRS - Agencija za raziskovalno dejavnost Republike Slovenije
• Številka projekta: P1-0153
• Naslov: Raziskave in razvoj analiznih metod in postopkov